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The radioactive waste processing operations aim at concentrating and containing the radioactivity in packages capable of being handled and stored provisionally until a decision is taken as to their long-term management. Basically, these operations comprise two steps :

firstly, reducing the waste volume to the maximum ;
secondly, stabilizing the waste in an immobilization matrix and containing it in a primary packaging.

(The whole [stabilization and containment] is also called conditioning.)



Reducing the volume

Reducing the volume aims at concentrating the radioactivity as much as possible in order to reduce the volume of materials considered to be radioactive waste. The techniques vary, depending on the nature of the waste.


Combustible solid waste is reduced to ashes in an industrial incinerator at a temperature of 900°C. The combustion gases are filtered and checked prior to being discharged into the atmosphere. The ashes are poured into a 200-litre steel drum, which is compacted under a 2,000-tonne press. The product obtained is a pellet with a maximum thickness of 40 cm.

Non-combustible solid waste that is compressible, is collected in the same type of steel drum, then compacted under the 2,000-tonne press. Non-compressible waste is cut up into pieces.


The pellets.
 

The volume of liquid radioactive waste can be reduced in two ways: chemical treatment, heat treatment or incineration.


Chemical treatment is a flocculation process, by which flakes are formed on which the radioactive substances are fixed. After settling, these flakes produce residual sludge which is filtered and dried, while the purified water is checked prior to being discharged.
Heat treatment consists in bringing the liquid waste to the boil, which leads to a residue in the form of radioactive sludge and steam, which is condensed then discharged after checking.
Certain organic or aqueous low-active liquid waste are treated in the same incinerator as the combustible solid waste. However, liquid and solid waste are never mixed during the combustion.


Stabilizing and containing

After the waste volume has been reduced, a compact, chemically stable and non-dispersible material must be obtained in order to facilitate subsequent handling.

Solid radioactive waste (pellets of compressed waste and non-compressible cut-up waste) is contained in cylindrical steel 400-litre drums resistant to corrosion (height: 1.07 m; diameter: 0.77 m). It is then stabilized by means of a matrix of cement, mortar or concrete, which is poured into the drums. When full, a drum weighs most often around 1 ton.

The radioactive sludge coming from the volume reduction of the liquid waste is dried, mixed in a homogeneous way with bitumen (stabilization) and poured into steel drums of 200 or 400 litres (containment).

Starting from raw and heterogeneous radioactive waste, a standard product is thus obtained: a 400-litre drum which can be easily handled. After being closed, every drum receives its own identification sheet indicating the origin, the radioactive inventory and the physical and chemical characteristics of its contents.

Section of a 400-litre drum, showing the various pellets and the immobilization matrix.


Where is radioactive waste processed ?

The great majority of radioactive waste produced and to be produced in Belgium, whether it is solid or liquid, of low, medium or high activity, is processed in the facilities of Belgoprocess in Dessel, at the same site where it will be stored provisionally until a decision is taken as to its long-term management (final disposal).
A part of the waste of the nuclear power plants is processed on the site of these power plants.


Spent nuclear fuel

Spent nuclear fuel from Belgian nuclear power stations is not processed at Belgoprocess. There are two technical options for its management :
reprocessing ;
storing it provisionally on the site of the nuclear power plants, if it cannot be reprocessed.

Reprocessing of spent nuclear fuel takes place in the factory of COGEMA in La Hague in France. The fuel rods are first cut into pieces. In order to reduce the volume of the materials considered to be radioactive waste, the nuclear fuel is then poured into nitric acid. The result of this dissolving is a radioactive liquid which contains 97% of reusable fuel - in the form of uranium and plutonium - and 3% of high-level waste, the fission products. The 97% of reusable fuel is used to manufacture new nuclear fuel (for example MOX). The 3% of high-level waste is vitrified, in other words mixed with a special molten glass (borosilicate glass) and poured into cylindrical stainless-steel containers where it solidifies to a homogeneous product in whose structure the radioactive substances are immobilized.


Molten glass leaving the furnace.
 


The containers which hold the waste from reprocessing Belgian spent nuclear fuel by COGEMA have a capacity of 150 litres and measure 1.34 m in height with a diameter of 0.43 m. When full, a container weighs on average 450 kg and releases a maximum amount of heat of 2,000 Watt, which is comparable to the heat emitted by an electric radiator. The contents of each container correspond to the reprocessing of 1,5 metric tons of spent fuel, or the quantity of fuel necessary to assure the electric consumption of about 116.000 Belgian households for one year.

 





(Illustration : mock-up of a stainless-steel container holding 400 kg of vitrified waste. The wall of the mock-up is open, showing the structure of the glass in black).

The stainless-steel containers temporarily at COGEMA must be transported to Belgium by rail (see our Transport section on this subject). There is indeed a storage building specially designed to accommodate them at the Belgoprocess site.

If you don't understand a term, please refer to our glossary.